WARDS NATURAL SCIENCE ESTABLISHMENT INC -- COPPER SULFATE PENTAHYDRATE -- -
===================== Product Identification ===================== Product ID:COPPER SULFATE PENTAHYDRATE MSDS Date:01/18/1995 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692 Country:US Info Phone Num:(716) 359-2502 OR 800-962-2660 Emergency Phone Num:800-424-9300 Resp. Party Other MSDS Num.:CC 535 Chemtrec Ind/Phone:(800)424-9300 CAGE:63759 === Contractor Identification === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-A-0024-0085 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER(II) SULFATE PENTAHYDRATE CAS:7758-99-8 RTECS #:GL8900000 = Wt:100. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INGESTION:ALTHOUGH A STRONG EMERIC, INGESTION CAN CAUSE COPPER POISONING AND/OR DEATH. EYES:CORROSIVE;CAUSE CONJUNCTIVITIS, SWELLING OF THE EYELIDS, ULCERATION AND BUN OF THE CORNEA. SKIN:CAUSES IRRIT ATION. MAY CAUSE ALLERGIC SKIN REACTION. INHALATION: CAUSES UPPER RESPIRATORY IRRITATION AND CONGESTION OF THE NASAL AND MUCOUS MEMBRANES. Effects of Overexposure:INGESTION: NAUSEA, VOMITING, DIARRHEA, GASTRIC PAIN, AND HEMORRHAGIC GASTRITIS. EYES: CORROSIVE, CONJUNCTIVITIS, SWELLING OF EYELIDS, ULCERATION, BURN OF CORNEA. SKIN:IRRITATION. ALLERGIC SKIN REACTIO N. INHALATION:UPPER RESPIRATORY IRRITATION AND CONGESTION OF NASAL AND MUCOUS MEMBRANES. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. IF ILLNESS OR DISCOMFORT DEVELOPS GET MED ATTN. EYES:FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MED ATTN. SKI N:FLUSH WITH WATER, THEN WASH WITH MILD SOAP AND WATER. INGESTION:IF SWALLOWED, IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF WATER TO DRINK, INDUCE VOMITING AND CALL PHYSICIAN. NEVER GIVE ANYTING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE ANY MEDIA SUITABLE FOR EXTINGUISHING SUPPROTING FIRE. Fire Fighting Procedures:IN FIRE CONDITIONS,WEAR A NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS.CUPRIC SULFATE WILL NOT BURN, NOR WILL IT SUPPORT COMBUSTION.IF DRY HEATED ABOVE 600C, SO2 IS EVOLVED. IF WAER IS USED, IT W ILL SOLUBILIZE THE CUSO4.5H2O, AND CARE SHOULD BE USED TO KEEP SUCH WATER OUT OF SSTREAMS OR OTHER WATER BODIES. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:SPRINKLE LIME OR SODA ASH ON SPILL TO FORM INSOLUBLE COPPER SALT. SWEEP UP AND PLACE IN SUITABLE CONTAINER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLSOED WHEN NOT IN USE. STORE IN COOL DRY PLACE. WASH THOROUGHLY AFTER HANDLING. Other Precautions:READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID CONTACT WITH SKIN OR EYES. AVOID BREATHING DUST. WASH CONTAMINATED CLOTHING BEFORE REUSE. FOR LABORA TORY USE ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. KEEP OUT OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE REQUIRED IN NORMAL LABORATORY USE. IF DUSTY CONDITONS PREVAIL, WORK IN A VENTILATION HOOD OR WEAR A NIOSH-APPROVED DUST MAST. Ventilation:LOCAL EXHAUST:RECOMMENDED. MECHANICAL (GENERAL):RECOMMENDED. Protective Gloves:RUBBER. Eye Protection:CHEMICAL SAFETY GLASSES. Other Protective Equipment:SAFETY GLASSES, SMOCK, APRON, VENTED HOOD, PROPER GLOVES, AND EYE WASH STATION. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. AVOD CONTACT WITH SKIN OR EYES. ABOIVE BREATHING DUST. WASH CONNTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ITEM #37-2238. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:=150.C, 302.F B.P. Text:-5H2O Melt/Freeze Pt:=150.C, 302.F M.P/F.P Text:-4H2O Vapor Pres:NEGLIGIBLE AS SOLID Vapor Density:8.64 Spec Gravity:2.284 @20C Evaporation Rate & Reference:NA Solubility in Water:24.3G/100ML@30C. Appearance and Odor:BLUE CRYSTALS OR FINE BLUE POWDER; NO ODOR. Percent Volatiles by Volume:SEE OTHER IN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN WHEN PRODUCT REMAINS DRY. SOLUTIONS ARE CORROSIVE TO MILD STEEL. NITRIC ACID. Stability Condition to Avoid:EXCESSIVE TEMPERATURE AND HEAT. Hazardous Decomposition Products:NONE AT NORMAL PROCESS TEMPERATURES AND PRESSURES. IF DRY HEATED ABOVE 1100F (600C) SULFUR DIOXIDE (SO2) MAY BE RELEASED. =================== Toxicological Information =================== Toxicological Information:TLV: (AIR) AS COPPER METAL: 1.0MG/M3 FOR 8HR. WORKING DAY. COPPER (FUME) TLV 0.2 MG/M3. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE, OR LOCAL LAWS. THESE DISPOSAL GUIDELINES ARE INTENDED FOR THE DISPOSAL OF CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF IN APPROVED CHEMI CAL LANDFILL OR CONTACT A LICENSED CHEMICAL WASTE DISPOSAL AGENCY. =================== MSDS Transport Information =================== Transport Information:DOT:NON-REGUALTED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.