FREY SCIENTIFIC -- PARA-DICHLOROBENZENE -- 6810-00D003593
===================== Product Identification ===================== Product ID:PARA-DICHLOROBENZENE MSDS Date:12/04/1992 FSC:6810 NIIN:00D003593 === Responsible Party === Company Name:FREY SCIENTIFIC Address:905 HICKORY LANE City:MANSFIELD State:OH ZIP:44905 Country:US Info Phone Num:419-589-9905 Emergency Phone Num:419-589-9905 Preparer's Name:ALEXANDER A. PICCIRILLI CAGE:6U218 === Contractor Identification === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44905 Country:US Phone:419-589-1900 CAGE:6U218 ============= Composition/Information on Ingredients ============= Ingred Name:P-DICHLOROBENZENE (1,4-DICHLOROBENZENE) (SARA 313) (CERCLA) CAS:106-46-7 RTECS #:CZ4550000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:75 PPM ACGIH TLV:10 PPM, A3; 9495 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 500 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, RESPIRATORY & GI TRACTS. ACUTE- CAN CAUSE SEVERE EYE IRRITATION & BURNS. SKIN CONTACT CAN CAUSE SLIGHT IRRITATION. INHALATION MAY CAUSE CNS DEPRESSION WITH SYMPTOMS OF DI ZZINESS, HEADACHE. INGESTION MAY CAUSE ABDOMINAL PAIN, CNS DEPRESSION, RESTLESSNESS, DIZZINESS. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, NAUSEA, VOMITING, MENTAL CONFUSION, FATIGUE, LOSS OF APPETITE, COUGH, BURNS, RESTLESSNESS, DIARRHEA Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK SEVERAL GLASSES OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. NEVER GIVE ANYTIHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:148F,64C Extinguishing Media:WATER SPRAY, DRY CHEMICAL (ABC), CARBON DIOXIDE, FOAM. COOL FIRE-EXPOSED CONTAINERS WITH WATER. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. SEE 1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE NO 58. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. CAN BURN WHEN IN CONTACT WITH FLAMES OR HOT SURFACES PRODUCING TOXIC AND CORROSIVE GASES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. WASH SPILL AREA WITH SOAP AND WATER. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT TAKE INTERNALLY. Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID INHALATION OF FUMES, VAPORS OR DUST. KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD/HOUSEHOLD U SE. USE WITH ADEQUATE VENTILATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING. IF REQUIRED, WORK IN A FUME HOOD OR WEAR A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR. IN EMERGENCY, WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPA RATUS. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:RUBBER Eye Protection:SAFETY GOGGLES/CHEMICAL SAFETY GLASSES Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING AND/OR UNIFORM Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:345F,174C Melt/Freeze Pt:M.P/F.P Text:127F,53C Vapor Pres:0.4 @ 77F Vapor Density:5.07 Spec Gravity:1.248 Evaporation Rate & Reference:<1 (WATER=1) Solubility in Water:INSOLUBLE Appearance and Odor:WHITE CRYSTALLINE SOLID; PENETRATING BUT PLEASANT AROMATIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT, DIRECT FLAME CONTACT Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE AND POSSIBLY TRACES OF PHOSGENE MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AN APPROVED INCINERATOR OR CONTRACT WITH LICENSED CHEMICAL WASTE DISPOSAL SERVICE. DISCHARGE, TREATMENT OR DISPOSAL IS SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. 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