TEXACO REFINING AND MARKETING INC -- 02624 DIESEL FUEL -- 9140-00N076893
===================== Product Identification ===================== Product ID:02624 DIESEL FUEL MSDS Date:12/08/1995 FSC:9140 NIIN:00N076893 === Responsible Party === Company Name:TEXACO REFINING AND MARKETING INC Box:7812 City:UNIVERSAL CITY State:CA ZIP:91608 Country:US Info Phone Num:914-838-7204 Emergency Phone Num:914-831-3400;800-424-9300(CHEMTREC) CAGE:2R503 === Contractor Identification === Company Name:TEXACO REFINING AND MARKETING INC Address:1111 RUSK ST Box:City:HOUSTON State:TX ZIP:77002-3310 Country:US Phone:713-650-5206 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCARBONS; (COMPLEX MIX OF HYDROCARBS PRDCED BY CRUDE OIL DISTIL. CONSISTS PREDOMINANTLY OF HYDROCARBS RANGING(ING 2) Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 1:FROM C-9 TO C-20, & BOILING IN RANGE OF 325-675F. HYDROTREATED/HYDROSULFURIZED PROD ALSO CONTAINS SOME (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:HYDROCARBS PRDCED BY DISTIL OF CATALYTIC CRACKING. LATTER MATLS CONTAIN BICYCLIC & TRICYCLIC AROMATIC HYDROCARBS.) RTECS #:9999999ZZ Ingred Name:CUMENE (SARA 313) (CERCLA). % (WT):0.01-0.09 CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: SEE ING OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE (SARA 313) (CERCLA). % (WT):0.01-0.90 CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: SEE ING OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SUPDAT:INFO:MIDDLE DISTIL HAVE CAUSED SKIN IRRIT & SKIN CANCER IN LAB ANIMALS WHEN RPTDLY APPLIED & LEFT IN PLACE(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:BETWEEN APPLIC. STUDIES TO FURTHER EVAL CARCIN POTNTL OF MIDDLE DISTIL ARE CURRENTLY UNDERWAY. KIDNEY DMG (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:HAS ALSO BEEN OBSERVED IN LAB ANIMALS EXPOS TO MIDDLE DISTIL. CHRONIC:NIOSH HAS REC WHOLE DIESEL EXHAUST (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:BE REGARDED AS POTNTL OCCUP CARCIN, BASED ON FINDINGS OF CARCIN RESPONSES IN LAB ANIMALS EXPOS TO WHOLE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:DIESEL EXHAUST. EXCESS CANCER RISK FOR WORKERS EXPOS TO DIESEL EXHAUST HAS NOT BEEN CALCULATED; (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:PROBABILITY OF DEVELOPING CANCER SHOULD BE DECR BY MINIMIZING EXPOS TO LOWEST FEASIBLE LIMS. RPTD SKIN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:CONT MAY CAUSE PERSISTENT IRRITATION OR DERMATITIS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:IS CONSCIOUS & CAN SWALLOW, GIVE 2 GLASSES OF WATER(16 OZ) BUT DO NOT INDUCE VOMIT. IF VOMIT (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:OCCURS, GIVE FLUIDS AGAIN. HAVE MED PERS DETERM IF EVAC OF STOM/INDUCTION OF VOMIT IS NEC. DO NOT GIVE (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:ANYTHING BY MOUTH TO UNCON/CONVL PERSON. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, CLEAR PERSON'S AIRWAY (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:GIVE ARTF RESP. IF BRTHG IS DFCLT, QUALIFIED MED PERS MAY ADMIN OXYG. GET MED ATTN IMMED. OTHER (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:INSTRUCTIONS:REMOVE & DRY-CLEAN/LAUNDER CLTHG SOAKED/SOILED W/THIS MATL BEFORE REUSE. DRY CLEANING OF (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:CONTAMD CLTHG MAY BE MORE EFTIVE THAN NORM LAUNDERING. INFORM INDIVIDUALS RESPONSIBLE FOR CLEANING OF (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:POTNTL HAZS ASSOC W/HNDLG CONTAMD CLTHG. ASPIR OF PROD DURING INDUCED EMESIS MAY RSLT IN SEV LUNG INJURY.(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:IF EVAC OF STOM IS NEC, USE METH LST LIKELY TO CAUSE ASPIR, SUCH AS GASTRIC LAVAGE AFTER ENDOTRACHEAL (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:INTUBATION. CONT POIS CTL CTR FOR ADDITIONAL TREATMENT INFORMATION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:>100,000 POUNDS OF PROD IS SPILLED, RPT SPILL ACCORD TO SARA 304 &/OR CERCLA 102(A) REQUIREMENTS, (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:UNLESS PROD QUALIFIES FOR PETROLEUM EXEMPTION (CERCLA SECTION 101(14)). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 9.00 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE IRRIT, EXPERIENCED AS MILD DISCOMFORT & SEEN AS SLIGHT EXCESS REDNESS OF EYE. SKIN:CAUSES SEV IRRIT W/PAIN, SEV EXCESS REDNESS & SWELL W/CHEM BURNS, BLISTER FORMATION, & POSS TISS DESTRUCTION. PRLNGD, WIDESPREAD/RPTD SKIN CONT MAY RSLT IN ABSORP OF POTNTLY HARMFUL AMTS OF MATL. (EFTS OF OVEREXP) Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG 120, 1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE (SUPDAT) Effects of Overexposure:HLTH HAZ:INHAL:VAPS/MIST MAY CAUSE IRRIT OF NOSE & THROAT. MAY CAUSE DIZZ, DROW, EUPHORIA, LOSS OF COORDINATION, DISORIENTATION, HDCH, NAUS, & VOMIT. IN POORLY VENTILATED AREAS/CONFINED SPACES, UNCON & ASPHY MAY RSLT. PRLNGD/RPTD OVEREXP MAY RSLT IN ABSORP OF POTNTLY HARMFUL AMTS OF MATL. INGEST:IF MORE THAN (SUPDAT) Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS (SKIN CONDITION). ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS. HOLD EYELIDS APART WHILE FLUSHING TO RINSE ENTIRE SURF OF EYE & LIDS W/WATER. GET MED ATTN. SKIN:IMMED REMOVE CONTAM CLTHG & SHOES. UNDER SFTY SHO WER, FLUSH SKIN THOROUGHLY W/LG AMTS OFRUNNING WATER FOR @ LST 15 MINS. DO NOT ATTEMPT TO NEUT W/CHEM AGENTS. GET MED ATTN IMMED. DISCARD/DECONTAM CLTHG & SHOES BEFORE REUSE. INGEST:IF PERSON(ING 14) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:125F,52C Lower Limits:0.5% Upper Limits:4.1% Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM/CARBON DIOXIDE TO EXTINGUISH FLAMES. USE WATER SPRAY TO COOL FIRE-EXPOSED CNTNRS. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . APPROACH FIRE FROM UPWIND TO AVOID HAZ VAPS & TOX DECOMP PRODS. DECONTAM/DISCARD ANY CLTHG CONTAINING CHEM (SUPDAT) Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. AVOID BRTHG VAP. WEAR APPROP PERSONAL PROT EQUIP, INCL APPROP NIOSH APPRVD RESP PROT. CONTAIN SPILL IF POSS. WIPE UP/ABSORB ON SUITABLE MATL & SHOVEL UP. PVNT ENTRY INTO SEWERS & WATER WAYS. AVOID CONT W/SKIN, EYES/CLTHG. IF(ING 23) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT & OPEN FLAME. PERIODS OF EXPOS TO HIGH TEMPS SHOULD BE MINIMIZED. WATER CONTAM SHOULD BE AVOIDED. KEEP AWAY FROM HEAT & FLAME. Other Precautions:AVOID BREATHING VAPOR, MIST, OR GAS. KEEP CONTAINER CLOSED. NEVER SIPHON BY MOUTH. USE ONLY WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION CONTACT NEHC . Ventilation:LOC EXHAUST VENT REC IF GENERATING VAP, DUST/MIST. IF EXHAUST VENT IS NOT AVAIL/INADEQ, USE NIOSH APPRVD RESP AS APPROP. Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . COVERALLS/LAB COATS, IMPERVIOUS SUITS, GLOVES, & RUBB BOOTS. Work Hygienic Practices:LAUNDER/DRY-CLEAN WHEN SOILED. AVOID CONT W/EYES, SKIN & CLTHG. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:RESIDUES. EXPLAN OF CARCIN: CARCIN FED REGISTER, VOL 52, PG 34460, 1987:OSHA-CANCER HAZ. HUMAN:MYELOID LEUKEMIA, HODGKINS DISEASE, LYMPHOMIA. EFTS OF OVEREXP:SEVERAL MOUTHFULS ARE SWAL LOWED, ABDOM DISCOMFORT, NAUS, & DIARR MAY OCCUR. ASPIR MAY OCCUR DURING SWALLOWING/VOMIT RSLTG IN LUNG DMG. TOX:(ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:650F,343C Vapor Pres:<10 @ 68F Spec Gravity:0.8521(WATER=1) Evaporation Rate & Reference:NOT KNOWN Solubility in Water:<0.1% Appearance and Odor:BRIGHT AND CLEAR LIQUID (TAX EXEMPT DIESELS-PALE RED LIQUID), PETROLEUM ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HEAT, STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:PRODS EVOLVED WHEN SUBJECTED TO HEAT/COMBUST:TOX LEVELS OF CO*2, CO, IRRITATING ALDEHYDES & KETONES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . FOR MORE SPECIFIC INFORMATION CONTACT NEHC . ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.