TEXACO INC. -- 00375 UNLEADED PLUS GASOLINE -- 9130-01-282-2844
===================== Product Identification ===================== Product ID:00375 UNLEADED PLUS GASOLINE MSDS Date:10/24/1990 FSC:9130 NIIN:01-282-2844 === Responsible Party === Company Name:TEXACO INC. Box:509 City:BEACON State:NY ZIP:12508-0509 Country:US Info Phone Num:914-831-3400 Emergency Phone Num:914-831-3400 Preparer's Name:M.J. VONALLMEN CAGE:38431 === Contractor Identification === Company Name:DIGITAL CONTROL SYSTEMS INC Address:3160 GRAND MARAIS E Box:City:WINDSOR, N8W 4W5 State:ON Country:CN Phone:NONE CAGE:38431 Company Name:SCHULTE OIL CO Address:1516 S ROCK ISLAND Box:188 City:EL RENO State:OK ZIP:73036 Country:US Phone:405-262-3120 CAGE:4R019 Company Name:TEXACO INC Box:509 City:BEACON State:NY ZIP:12508-0509 Country:US Phone:914-831-3400 CAGE:7B131 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 1-3.99% Other REC Limits:NONE SPECIFIED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 4-10.99% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1-3.99% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4-10.99% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-3.99% Other REC Limits:NONE SPECIFIED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9192 Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: 0-15% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 95-99.9% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9293 Ingred Name:ALIPHATIC PETROLEUM SOLVENT CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: .01-.09% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM PETR. DIST. ACGIH TLV:400 PPM RUBBER SOLV. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) = 18.75 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES:SLIGHT TO MODERATE IRRITATION.SKIN:MODERATELY IRRITATING.DERMALLY ABSORBED;LD50 DERMAL RABBIT>5MG/KG.INHAL:IRRITATES EYES,NOSE,THROAT.CAUSES CNS EFFECTS. INGEST:MAY CAUSE LUNG DAMAGE IF VOMITTED AFTER SWALLOWING.CHRONIC-GASOLINE VAPORS MAY CAUSE LIVER AND KIDNEY DAMAGE. Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:SKIN:REDNESS,EDEMA,DRYING.INHAL:CNS EFFECTS-DIZZINESS,BLUISH SKIN COLOR. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING;WASH EXPOSED AREA WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING! CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. G IVE ARTIFICIAL RESPIRATION OR OXYGEN IFNEEDED.CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:-40F,-40C Lower Limits:1.4 % Upper Limits:7.6 % Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS. USE A SELF-CONTAINED BRETAHING APPARATUS AND FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND TRAVEL ALONG THE FLOOR;FLOWING GASOLINE GENERATES STATIC ELECTRICITY ...THIS PRESENTS A FLASHBACK HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA. AVOID BREATHING VAPORS. USE SCBA FOR LARGE SPILLS OR IN CONFINED AREAS. CONTAIN SPILL IF POSSIBLE. REMOVE WITH NON-FLAMMABLE ADSORBANT(EG.DIATOMACEOUS EARTH );PLACE IN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:TRANSPORT, HANDLE AND STORE IN ACCORDANCE WITH OSHA REGULATION 1910.106 AND APPLICABLE D.O.T. REGULATIONS. Other Precautions:DANGER! EXTREMELY FLAMMABLE. HARMFUL OR FATAL IF SWALLOWED! ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA OR SUPPLIED AIR RESPIRATORY PROTECTION REQUIRED FOR ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES. Ventilation:ADEQUATE TO MEET PERMISSIBLE CONCENTRATIONS. Protective Gloves:NITRILE, TEFLON, VITON Eye Protection:CHEMICAL-TYPE GOGGLES, FACE SHIELD Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS, COVERALLS OR LAB COATS SHOULD BE WORN. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:>90F,>32C Vapor Pres:465-775 Vapor Density:3 - 4.0 Spec Gravity:0.7 - .77 Evaporation Rate & Reference:N.D. Solubility in Water:SLIGHT Appearance and Odor:LIQUID;LIGHT STRAW TO LIGHT RED;GASOLINE ODOR Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSIDERED RCRA HAZARDOUS WASTE;IT IS TOXIC(BENZENE) AND IGNITABLE(FP=-40F).DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.